New PDF release: Alkene Metathesis in Organic Synthesis (Topics in

By Alois Fuerstner

ISBN-10: 3540642544

ISBN-13: 9783540642541

The great growth in olefin metathesis completed over the last decade can rarely be overvalued. because of the improvement of a brand new iteration of good outlined and high-performance organometallic catalysts, this response is quickly evolving into essentially the most flexible instruments for complicated natural chemistry, ordinary product synthesis, high-quality chemical construction and polymer sciences. Written through a number of the top specialists during this box, this monograph intends to familiarize the reader with the main intriguing advancements and frontiers during this flourishing box of chemistry study.

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58. 59. 60. 61. 62. 63. 64. 65. 66. 67. 68. 69. 70. 71. 72. 73. 74. 75. 76. 77. 78. 79. 80. 81. Richard R. Schrock Peters JU, Blechert S (1997) Chem Commun 1983 Feldman J, Schrock RR (1991) Prog Inorg Chem 39:1 Buhro WE, Chisholm MH (1987) Adv Organometal Chem 27:311 Breslow DS (1993) Progress in Polymer Science 18:1141 Streck R (1988) J Mol Catal 46:305 Nugent WA, Feldman J, Calabrese JC (1995) J Am Chem Soc 117:8992 Xu Z, Johannes CW, Houri AF, La DS, Cogan DA, Hofilena GE, Hoveyda AH (1997) J Am Chem Soc 119:10302 Parkin G, Bunel E, Burger BJ, Trimmer MS, van Asselt A, Bercaw JE (1987) J Molec Catal 41:21 Freundlich JS, Schrock RR, Davis WM (1996) J Am Chem Soc 118:3643 Freundlich JS, Schrock RR, Davis WM (1996) Organometallics 15:2777 Edwards DS, Biondi LV, Ziller JW, Churchill MR, Schrock RR (1983) Organometallics 2:1505 van der Schaff PA, Hafner A, Mühlebach A (1996) Angew Chem Int Ed Engl 35:1845 Johnson LK, Frey M, Ulibarri TA, Virgil SC, Grubbs RH, Ziller JW (1993) J Am Chem Soc 115:8167 Sharp PR, Schrock RR (1979) J Organometal Chem 171:43 Wengrovius JH, Schrock RR (1982) Organometallics 1:148 Binger P, Müller P, Benn R, Mynott R (1989) Angew Chem 101:647 Johnson LK, Grubbs RH, Ziller JW (1993) J Am Chem Soc 115:8130 de la Mata FJ, Grubbs RH (1996) Organometallics 15:577 de la Mata FJ (1996) J Organomet Chem 525:183 Wu Z, Wheeler DR, Grubbs RH (1992) J Am Chem Soc 114:146 Murdzek JS, Schrock RR (1988) In: (ed) Carbyne complexes.

6 . . . . . . . . . . . . . . . . . . 63 64 64 66 66 . . . . 66 References . . . . . . . . . . . . . . . . . 70 1 Introduction The metathesis activity of various simple ruthenium compounds has already been discerned during early studies on the ring opening metathesis polymerization (ROMP) of norbornene and other cycloalkene substrates [1, 2]. A real breakthrough, however, was achieved when Grubbs et al. reported in the early 1990s that ruthenium-carbene complexes of the general type 1 are highly active single component (pre)catalysts for any kind of olefin metathesis reaction (Fig.

38 A. Fürstner 5 Selected Applications of RCM to Target Oriented Synthesis . . . 6 Carbocyclic Nucleosides . . . . . . . . . . Manzamine A . . . . . . . . . . . . . Epothilone A . . . . . . . . . . . . . (+)-Lasiodiplodin . . . . . . . . . . . Tricolorin A . . . . . . . . . . . . . (-)-Gloeosporone: Development of a Binary Metathesis Catalyst System . . . . . . . . . . . . 6 . . . . . . . . . . . . . . .

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Alkene Metathesis in Organic Synthesis (Topics in Organometallic Chemistry) (Vol 1) by Alois Fuerstner


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