M.F. Semmelhack's Additions to and Substitutions at C-C &pgr;-Bonds, Volume 4 PDF

By M.F. Semmelhack

ISBN-10: 0080405959

ISBN-13: 9780080405957

Quantity four specializes in additions and the ensuing substitutions at carbon-carbon &pgr;-bonds. half 1 contains tactics often regarded as basic polar reactions, reactive electrophiles and nucleophiles including to alkenes and alkynes. a tremendous subject is Michael-type addition to electron poor &pgr;-bonds, featured within the first six chapters. partly 2 are accrued the 4 common procedures resulting in nucleophilic fragrant substitution, together with radical chain approaches and transition steel activation via to &pgr;-complexation. Metal-activated addition (generally by means of nucleophiles) to alkenes and polyenes is gifted partly three, together with allylic alkylation catalyzed through palladium. The insurance of nonpolar additions partially four comprises radical additions, organometal addition (Heck reaction), carbene addition, and 1,3-dipolar cycloadditions.

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Quantity four specializes in additions and the ensuing substitutions at carbon-carbon &pgr;-bonds. half 1 contains techniques usually regarded as easy polar reactions, reactive electrophiles and nucleophiles including to alkenes and alkynes. a big subject is Michael-type addition to electron poor &pgr;-bonds, featured within the first six chapters.

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